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Splitting and reorientation of pi-conjugation by an unprecedented photo-rearrangement reaction

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Title: Splitting and reorientation of pi-conjugation by an unprecedented photo-rearrangement reaction
Authors: Inaba, Yuya Browse this author
Yoneda, Tomoki Browse this author
Kitagawa, Yuichi Browse this author
Miyata, Kiyoshi Browse this author
Hasegawa, Yasuchika Browse this author
Inokuma, Yasuhide Browse this author →KAKEN DB
Issue Date: 11-Jan-2020
Publisher: Royal Society of Chemistry
Journal Title: Chemical communications
Volume: 56
Issue: 3
Start Page: 348
End Page: 351
Publisher DOI: 10.1039/c9cc09062b
Abstract: A dodecahexaene analogue cross-conjugated with four carbonyl groups was prepared from an aliphatic tetraketone. Exposure to LED light (>420 nm) led to the splitting of the dodecahexaene conjugation into two hexatriene subunits, connected through a stereogenic carbon atom. The two triene subunits exhibited excitonic coupling in the UV-Vis absorption and CD spectra.
Type: article (author version)
URI: http://hdl.handle.net/2115/80132
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 猪熊 泰英

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