|
Hokkaido University Collection of Scholarly and Academic Papers >
Graduate School of Engineering / Faculty of Engineering >
Peer-reviewed Journal Articles, etc >
Highly luminescent tetranuclear Eu(III) complex with characteristic cavity space
This item is licensed under:Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
| Title: | Highly luminescent tetranuclear Eu(III) complex with characteristic cavity space |
| Authors: | Koizuka, Toru Browse this author | | Kitagawa, Yuichi Browse this author | | Nakanishi, Takayuki Browse this author →KAKEN DB | | Fushimi, Koji Browse this author →KAKEN DB | | Hasegawa, Yasuchika Browse this author →KAKEN DB |
| Keywords: | Tetranuclear | | Complex | | Luminescence | | Europium | | Sensor |
| Issue Date: | 24-Feb-2019 |
| Publisher: | Elsevier |
| Journal Title: | Inorganica chimica acta |
| Volume: | 486 |
| Start Page: | 240 |
| End Page: | 244 |
| Publisher DOI: | 10.1016/j.ica.2018.10.063 |
| Abstract: | Novel luminescent tetranuclear Eu(III) complex [Eu(btfa)(3)(salbn)](4) (btfa: benzoyltrifluoroacetonate, salbn: N,N'-bis(salicylidene)-1,4-butanediamine) with characteristic cavity space is reported. The Eu(III) complex excited at 480 nm exhibits the highest photosensitized emission quantum yield (36%) reported for similar previously reported tetranuclear Eu(III) complexes. The Eu(III) complex with salbn and btfa also showed the spectral change under addition of K+ and Zn2+ ions. In this study, we demonstrated metal ions sensor ability of a highly luminescent Eu(III) complex. |
| Rights: | © 2019. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ | | http://creativecommons.org/licenses/by-nc-nd/4.0/ |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/80477 |
| Appears in Collections: | 工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
|
Submitter: 長谷川 靖哉
|
