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Flotation Separation of Chalcopyrite and Molybdenite Assisted by Microencapsulation Using Ferrous and Phosphate Ions: Part II. Flotation

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Title: Flotation Separation of Chalcopyrite and Molybdenite Assisted by Microencapsulation Using Ferrous and Phosphate Ions: Part II. Flotation
Authors: Park, Ilhwan Browse this author →KAKEN DB
Hong, Seunggwan Browse this author
Jeon, Sanghee Browse this author →KAKEN DB
Ito, Mayumi Browse this author →KAKEN DB
Hiroyoshi, Naoki Browse this author →KAKEN DB
Keywords: porphyry deposits
chalcopyrite
molybdenite
microencapsulation
flotation
Issue Date: Mar-2021
Publisher: MDPI
Journal Title: Metals
Volume: 11
Issue: 3
Start Page: 439
Publisher DOI: 10.3390/met11030439
Abstract: Porphyry-type deposits are the major sources of copper and molybdenum, and flotation has been adopted to recover them separately. The conventional reagents used for depressing copper minerals, such as NaHS, Na2S, and Nokes reagent, have the potential to emit toxic H2S gas when pulp pH was not properly controlled. Thus, in this study the applicability of microencapsulation (ME) using ferrous and phosphate ions as an alternative process to depress the floatability of chalcopyrite was investigated. During ME treatment, the use of high concentrations of ferrous and phosphate ions together with air introduction increased the amount of FePO4 coating formed on the chalcopyrite surface, which was proportional to the degree of depression of its floatability. Although ME treatment also reduced the floatability of molybdenite, similar to 92% Mo could be recovered by utilizing emulsified kerosene. Flotation of chalcopyrite/molybdenite mixture confirmed that the separation efficiency was greatly improved from 10.9% to 66.8% by employing ME treatment as a conditioning process for Cu-Mo flotation separation.
Rights: https://creativecommons.org/licenses/by/4.0/
Type: article
URI: http://hdl.handle.net/2115/81269
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

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