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Peer-reviewed Journal Articles, etc >
Synthesis and Optical Properties of C,N-Swapped Boranils Derived from Potassium Acyltrifluoroborates
| Title: | Synthesis and Optical Properties of C,N-Swapped Boranils Derived from Potassium Acyltrifluoroborates |
| Authors: | Matsuura, Satsuki Browse this author | | Taguchi, Jumpei Browse this author | | Seki, Tomohiro Browse this author | | Ito, Hajime Browse this author →KAKEN DB |
| Keywords: | Acylboron compounds | | Boron-containing heterocycles | | Photoluminescence |
| Issue Date: | May-2021 |
| Publisher: | 日本化学会（Chemical Society of Japan） |
| Journal Title: | Bulletin of the chemical society of Japan |
| Volume: | 94 |
| Issue: | 5 |
| Start Page: | 1547 |
| End Page: | 1552 |
| Publisher DOI: | 10.1246/bcsj.20210024 |
| Abstract: | Novel C,O-chelated bora-heterocycles were synthesized. Reaction of potassium acyltrifluoroborates with tetrahydroquinolin-8-ol furnished C,N-swapped boranils in a single step. All five obtained borates showed photoluminescence in solid state. One of them showed yellow-to-orange reversible mechano-chromic luminescence. Further derivatization afforded a B-chiral borate with an O,C, O-tridentate ligand that showed significant thermochromism. |
| Type: | article |
| URI: | http://hdl.handle.net/2115/82484 |
| Appears in Collections: | 工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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