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Pincer-Type Phosphorus Compounds with Boryl-Pendant and Application in Catalytic H-2 Generation from Ammonia-Borane: A Theoretical Study
Title: | Pincer-Type Phosphorus Compounds with Boryl-Pendant and Application in Catalytic H-2 Generation from Ammonia-Borane: A Theoretical Study |
Authors: | Yang, Deshuai Browse this author | Bao, Panqing Browse this author | Yang, Zhen Browse this author | Chen, Zhaoxu Browse this author | Sakaki, Shigeyoshi Browse this author | Maeda, Satoshi Browse this author →KAKEN DB | Zeng, Guixiang Browse this author |
Keywords: | ammonia borane | theoretical study | dehydrogenation | pincer-type phosphorus | phosphorus-boryl cooperation |
Issue Date: | 3-Sep-2021 |
Publisher: | Wiley-Blackwell |
Journal Title: | ChemCatChem |
Volume: | 13 |
Issue: | 18 |
Start Page: | 3925 |
End Page: | 3929 |
Publisher DOI: | 10.1002/cctc.202100661 |
Abstract: | Metal-free catalysts composed of heavy main group element(s) have been limited. Herein, a theoretical study unveils that pincer-type phosphorus compound bearing a boryl-pendant is good catalyst for H-2 generation from ammonia borane through phosphorus-boryl (P-B) cooperation function. Pincer-type phosphorus compound without boryl-pendant is not active for this reaction, indicating the important role of the P-B cooperation function. |
Type: | article |
URI: | http://hdl.handle.net/2115/82595 |
Appears in Collections: | 理学院・理学研究院 (Graduate School of Science / Faculty of Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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