Synthesis of hydrosilylboronates via the monoborylation of a dihydrosilane Si-H bond and their application for the generation of dialkylhydrosilyl anions


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Title:	Synthesis of hydrosilylboronates via the monoborylation of a dihydrosilane Si-H bond and their application for the generation of dialkylhydrosilyl anions
Authors:	Takeuchi, Takumi Browse this author
	Shishido, Ryosuke Browse this author
	Kubota, Koji Browse this author
	Ito, Hajime Browse this author →KAKEN DB
Issue Date:	21-Sep-2021
Publisher:	Royal Society of Chemistry
Journal Title:	Chemical science
Volume:	12
Issue:	35
Start Page:	11799
End Page:	11804
Publisher DOI:	10.1039/d1sc01440d
Abstract:	The synthesis of a series of hydrosilylboronates via the selective iridium- or nickel-catalyzed monoborylation of dihydrosilane Si-H bonds is described. The synthesized silylboronates, which bear a single Si-H bond, can be used as novel silicon nucleophiles in the presence of transition-metal catalysts or bases. The first Si-29{H-1} NMR spectroscopic evidence for the formation of (t-Bu)(2)HSiLi, generated by the reaction of (t-Bu)(2)HSi-B(pin) with MeLi, is reported as the first example of a dialkylhydorosilyl lithium species.
Type:	article
URI:	http://hdl.handle.net/2115/82677
Appears in Collections:	工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

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