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Improvement of flotation and suppression of pyrite oxidation using phosphate-enhanced galvanic microencapsulation (GME) in a ball mill with steel ball media

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Title: Improvement of flotation and suppression of pyrite oxidation using phosphate-enhanced galvanic microencapsulation (GME) in a ball mill with steel ball media
Authors: Seng, Sophea Browse this author
Tabelin, Carlito Baltazar Browse this author
Makino, Yuta Browse this author
Chea, Monyneath Browse this author
Phengsaart, Theerayut Browse this author
Park, Ilhwan Browse this author
Hiroyoshi, Naoki Browse this author →KAKEN DB
Ito, Mayumi Browse this author →KAKEN DB
Keywords: Galvanic interactions
Galvanic microencapsulation
Ball mill
Flotation
Pyrite
Passivation
Issue Date: Nov-2019
Publisher: Elsevier
Journal Title: Minerals engineering
Volume: 143
Start Page: 105931
Publisher DOI: 10.1016/j.mineng.2019.105931
Abstract: Acid mine drainage (AMD) is one of the biggest and most challenging environmental concerns of the mining and mineral processing industries. In our previous study, we reported a new and promising approach to passivate sulfide minerals and limit AMD formation called galvanic microencapsulation (GME), a technique that forms protective coatings via galvanic interactions between sulfide minerals (e.g., pyrite) and metal powders (e.g., zero-valent iron and aluminum). In this paper, the possible application of GME in a ball mill with steel ball media and phosphate to suppress pyrite floatability during coal cleaning and limit pyrite oxidation after disposal is proposed. The results showed that adding phosphate and maintaining sufficient oxygen supply during GME treatment in the ball mill passivated pyrite and suppressed its oxidation via the formation of protective iron phosphate coatings. Moreover, the iron phosphate coatings on pyrite made the mineral more hydrophilic, which improved the separation efficiency during coal flotation.
Rights: © 2019. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
http://creativecommons.org/licenses/by-nc-nd/4.0/
Type: article (author version)
URI: http://hdl.handle.net/2115/83116
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 伊藤 真由美

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