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Liquid-liquid interface-promoted formation of a porous molecular crystal based on a luminescent platinum(ii) complex
| Title: | Liquid-liquid interface-promoted formation of a porous molecular crystal based on a luminescent platinum(ii) complex |
| Authors: | Kimura, Mari Browse this author | | Yoshida, Masaki Browse this author →KAKEN DB | | Fujii, Sho Browse this author | | Miura, Atsushi Browse this author | | Ueno, Kosei Browse this author | | Shigeta, Yasuhiro Browse this author | | Kobayashi, Atsushi Browse this author | | Kato, Masako Browse this author →KAKEN DB |
| Issue Date: | 4-Nov-2020 |
| Publisher: | Royal Society of Chemistry |
| Journal Title: | Chemical communications |
| Volume: | 56 |
| Issue: | 85 |
| Start Page: | 12989 |
| End Page: | 12992 |
| Publisher DOI: | 10.1039/d0cc04164e |
| Abstract: | Porous molecular crystals (PMCs) should function as new-generation functional porous materials, but the selective crystallisation of PMCs is still difficult. Herein we demonstrate that the liquid-liquid interface between the MeOH/H2O mixture and alkanes promotes the crystallisation of a Pt(ii)-based PMC, rather than the nonporous form. This new crystallisation method allows control of not only the porosity but also the luminescence of the Pt(ii) complex crystal. |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/83158 |
| Appears in Collections: | 理学院・理学研究院 (Graduate School of Science / Faculty of Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 加藤 昌子
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