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Fast discharge–charge properties of FePS3 electrode for all-solid-state batteries using sulfide electrolytes and its stable diffusion path

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Title: Fast discharge–charge properties of FePS3 electrode for all-solid-state batteries using sulfide electrolytes and its stable diffusion path
Authors: Fujii, Yuta Browse this author
Ito, Hiroaki Browse this author
Miura, Akira Browse this author →KAKEN DB
Rosero-Navarro, Nataly Carolina Browse this author
Tadanaga, Kiyoharu Browse this author →KAKEN DB
Lu, Li Browse this author
Keywords: Diffusion path
Galvanostatic Intermittent Titration Technique (GITT) Measurement
iron
Issue Date: 18-Mar-2021
Publisher: World Scientific
Journal Title: Functional Materials Letters
Volume: 14
Issue: 3
Start Page: 2141005
Publisher DOI: 10.1142/S1793604721410058
Abstract: We report the fast discharge–charge cycle of micro-sized FePS3 electrode particles in all-solid-state batteries (ASSBs) using sulfide electrolytes at 80°C. At a current density of 2.04 mA cm−2, corresponding to approximately 1 C, the capacity of the FePS3 electrodes reached ∼180 mAh g−1 without any electron or lithium-ion conductive additives. Galvanostatic intermittent titration technique (GITT) measurements showed a stable diffusion path of FePS3 represented by the product of the diffusion coefficient and square of the surface area. These electrochemical properties were compared with those of FeS, whose capacity was lower because of its unstable diffusion path.
Rights: Electronic version of an article published as [Journal, Volume, Issue, Year, Pages] [Article DOI] © [copyright World Scientific Publishing Company] [Journal URL]
Type: article (author version)
URI: http://hdl.handle.net/2115/84420
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 三浦 章

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