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Fast discharge–charge properties of FePS3 electrode for all-solid-state batteries using sulfide electrolytes and its stable diffusion path
Title: | Fast discharge–charge properties of FePS3 electrode for all-solid-state batteries using sulfide electrolytes and its stable diffusion path |
Authors: | Fujii, Yuta Browse this author | Ito, Hiroaki Browse this author | Miura, Akira Browse this author →KAKEN DB | Rosero-Navarro, Nataly Carolina Browse this author | Tadanaga, Kiyoharu Browse this author →KAKEN DB | Lu, Li Browse this author |
Keywords: | Diffusion path | Galvanostatic Intermittent Titration Technique (GITT) Measurement | iron |
Issue Date: | 18-Mar-2021 |
Publisher: | World Scientific |
Journal Title: | Functional Materials Letters |
Volume: | 14 |
Issue: | 3 |
Start Page: | 2141005 |
Publisher DOI: | 10.1142/S1793604721410058 |
Abstract: | We report the fast discharge–charge cycle of micro-sized FePS3 electrode particles in all-solid-state batteries (ASSBs) using sulfide electrolytes at 80°C. At a current density of 2.04 mA cm−2, corresponding to approximately 1 C, the capacity of the FePS3 electrodes reached ∼180 mAh g−1 without any electron or lithium-ion conductive additives. Galvanostatic intermittent titration technique (GITT) measurements showed a stable diffusion path of FePS3 represented by the product of the diffusion coefficient and square of the surface area. These electrochemical properties were compared with those of FeS, whose capacity was lower because of its unstable diffusion path. |
Rights: | Electronic version of an article published as [Journal, Volume, Issue, Year, Pages] [Article DOI] © [copyright World Scientific Publishing Company] [Journal URL] |
Type: | article (author version) |
URI: | http://hdl.handle.net/2115/84420 |
Appears in Collections: | 工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 三浦 章
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