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A Kinetic Study on Enhanced Cementation of Gold Ions by Galvanic Interactions between Aluminum (Al) as an Electron Donor and Activated Carbon (AC) as an Electron Mediator in Ammonium Thiosulfate System

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Title: A Kinetic Study on Enhanced Cementation of Gold Ions by Galvanic Interactions between Aluminum (Al) as an Electron Donor and Activated Carbon (AC) as an Electron Mediator in Ammonium Thiosulfate System
Authors: Jeon, Sanghee Browse this author →KAKEN DB
Bright, Sharrydon Browse this author
Park, Ilhwan Browse this author →KAKEN DB
Kuze, Akuru Browse this author
Ito, Mayumi Browse this author →KAKEN DB
Hiroyoshi, Naoki Browse this author →KAKEN DB
Keywords: gold
cementation
galvanic interaction
aluminum
activated carbon
kinetics
ammonium thiosulfate solution
mass transfer
Issue Date: Jan-2022
Publisher: MDPI
Journal Title: Minerals
Volume: 12
Issue: 1
Start Page: 91
Publisher DOI: 10.3390/min12010091
Abstract: The enhanced cementation technique by galvanic interaction of aluminum (Al; electron donor) and activated carbon (AC; electron mediator) to recover gold (Au) ions from the ammonium thiosulfate solution is a promising technique to eliminate the challenges of poor recovery in the system. This study presents the kinetics of Au ion cementation in an ammonium thiosulfate lixiviant as functions of initial Au concentration, size/amount of Al and AC, temperature, and shaking speed. The recovery results basically followed first order kinetics and showed that the cementation rate increased with a higher initial concentration of Au, smaller electron donor size, greater both electron donor and mediator quantity, decrease in temperature, and higher shaking speed in the system, while size of electron mediator did not significantly affect Au recovery.
Rights: © 2022 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/).
Type: article
URI: http://hdl.handle.net/2115/85048
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

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