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Chiral Carboxylic Acid Assisted Enantioselective C-H Activation with Achiral (CpMIII)-M-x (M = Co, Rh, Ir) Catalysts
| Title: | Chiral Carboxylic Acid Assisted Enantioselective C-H Activation with Achiral (CpMIII)-M-x (M = Co, Rh, Ir) Catalysts |
| Authors: | Yoshino, Tatsuhiko Browse this author →KAKEN DB | | Matsunaga, Shigeki Browse this author →KAKEN DB |
| Keywords: | C-H activation | | asymmetric catalysis | | chiral carboxylic acid | | cobalt | | rhodium | | iridium |
| Issue Date: | 17-May-2021 |
| Publisher: | American Chemical Society |
| Journal Title: | ACS catalysis |
| Volume: | 11 |
| Issue: | 11 |
| Start Page: | 6455 |
| End Page: | 6466 |
| Publisher DOI: | 10.1021/acscatal.1c01351 |
| Abstract: | Enantioselective C-H functionalization is a powerful tool for synthesizing chiral molecules. In the past few years, the combination of high-valent group 9 metals with achiral Cp-x ligands and chiral carboxylic acids (CCA) has emerged as a promising catalytic system to enable selective cleavage and functionalization of enantiotopic C-H bonds. This Perspective summarizes the background, catalyst design, and applied reactions in detail, followed by a discussion of future directions. |
| Rights: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS catalysis, copyright c American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/articlesonrequest/AOR-JSZYU629QNPSRBXEYQPX. |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/85464 |
| Appears in Collections: | 薬学研究院 (Faculty of Pharmaceutical Sciences) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 吉野 達彦
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