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Development of a Sustainable Process for Complex Sulfide Ores Containing Anglesite: Effect of Anglesite on Sphalerite Floatability, Enhanced Depression of Sphalerite by Extracting Anglesite, and Recovery of Extracted Pb2+ as Zero-Valent Pb by Cementation

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Title: Development of a Sustainable Process for Complex Sulfide Ores Containing Anglesite: Effect of Anglesite on Sphalerite Floatability, Enhanced Depression of Sphalerite by Extracting Anglesite, and Recovery of Extracted Pb2+ as Zero-Valent Pb by Cementation
Authors: Aikawa, Kosei Browse this author
Ito, Mayumi Browse this author →KAKEN DB
Kusano, Atsuhiro Browse this author
Jeon, Sanghee Browse this author →KAKEN DB
Park, Ilhwan Browse this author →KAKEN DB
Hiroyoshi, Naoki Browse this author →KAKEN DB
Keywords: flotation
complex sulfide ores
sphalerite
anglesite
extraction
cementation
Issue Date: Jun-2022
Publisher: MDPI
Journal Title: Minerals
Volume: 12
Issue: 6
Start Page: 723
Publisher DOI: 10.3390/min12060723
Abstract: The presence of anglesite (PbSO4) in complex sulfide ores negatively affects the separation of Cu-Pb sulfides and sphalerite (ZnS) due to lead activation, and PbSO4 rejected to tailings dams contaminates the surrounding environment with lead. To address these problems, this study investigated the application of ethylene diamine tetra acetic acid (EDTA) pretreatment extracting PbSO4 to ZnS flotation and the recovery of the extracted Pb2+ as zero-valent Pb by cementation using zero-valent iron (ZVI). The application of EDTA pretreatment could extract similar to 99.8% of PbSO4, thus depressing ZnS floatability from 82% to 30%. In addition, cementation using ZVI could recover similar to 99.7% of Pb2+ from the leachate of EDTA pretreatment.
Rights: © 2022 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/).
Type: article
URI: http://hdl.handle.net/2115/86447
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

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