One-pot synthesis of tetrasubstituted 2-aminofurans via Au(i)-catalyzed cascade reaction of ynamides with propargylic alcohols


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Title:	One-pot synthesis of tetrasubstituted 2-aminofurans via Au(i)-catalyzed cascade reaction of ynamides with propargylic alcohols
Authors:	Miyairi, Asaki Browse this author
	Oonishi, Yoshihiro Browse this author →KAKEN DB
	Sato, Yoshihiro Browse this author →KAKEN DB
Issue Date:	22-Oct-2021
Publisher:	Royal Society of Chemistry
Journal Title:	Organic & biomolecular chemistry
Volume:	19
Issue:	43
Start Page:	9396
End Page:	9400
Publisher DOI:	10.1039/d1ob01910d
Abstract:	One-pot synthesis of fully substituted 2-aminofurans via a Au(i)-catalyzed cascade reaction of ynamides and propargylic alcohol was realized. Hydroalkoxylation of ynamide with propargylic alcohol, Saucy-Marbet rearrangement, and cyclization of the resultant 3,4-dienamide sequentially proceeds in a one-pot reaction under highly mild conditions to give fully substituted 2-aminofurans.
Type:	article (author version)
URI:	http://hdl.handle.net/2115/87013
Appears in Collections:	薬学研究院 (Faculty of Pharmaceutical Sciences) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 大西英博

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