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Evaluation of Corrosion Progress Using Multichannel Iron Wire Electrodes Embedded in a Cement Test Block

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Title: Evaluation of Corrosion Progress Using Multichannel Iron Wire Electrodes Embedded in a Cement Test Block
Authors: Azumi, Kazuhisa Browse this author →KAKEN DB
Saito, Shu Browse this author
Ishida, Kou Browse this author
Keywords: concrete
neutralization
carbonation
impedance
electric resistance
Issue Date: 15-Sep-2022
Publisher: 一般社団法人 日本鉄鋼協会 (The Iron and Steel Institute of Japan)
Journal Title: ISIJ international
Volume: 62
Issue: 9
Start Page: 1937
End Page: 1945
Publisher DOI: 10.2355/isijinternational.ISIJINT-2022-192
Abstract: Eight thin iron wires were embedded in a cement test block to evaluate corrosion behavior during cement carbonization by CO2 absorption. The gases supplied sequentially to the chamber containing the cement test block were air, CO2, and then air. Electrical resistance measurement of the thin wires revealed that the iron wires remained passivated during the supply of air and uncorroded during the supply of CO2 to promote carbonization. The iron wires started corroding from the surface when the air was resupplied after carbonization due to the presence of O-2 in the air as an oxidizing agent. A set of two-electrode impedances between two selected iron wires was measured as a function of depth from the surface. The impedance of all electrodes dropped considerably several hours after the CO2 supply due to the difference in the immersion potential of the iron wires as a function of depth, that is, the pH transition from alkaline to neutral. Consequently, the iron wires were polarized when electrically connected to each other during carbonization. After carbonization, each iron wire showed an impedance response corresponding to its corrosion condition, which depended on its depth.
Type: article
URI: http://hdl.handle.net/2115/87025
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

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