Ruthenium(II)/Chiral Carboxylic Acid Catalyzed Enantioselective C-H Functionalization of Sulfoximines


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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/87116

Title:	Ruthenium(II)/Chiral Carboxylic Acid Catalyzed Enantioselective C-H Functionalization of Sulfoximines
Authors:	Huang, Long-Tao Browse this author
	Hirata, Yuki Browse this author
	Kato, Yoshimi Browse this author
	Lin, Luqing Browse this author
	Kojima, Masahiro Browse this author →KAKEN DB
	Yoshino, Tatsuhiko Browse this author →KAKEN DB
	Matsunaga, Shigeki Browse this author →KAKEN DB
Keywords:	ruthenium catalysis
	C-H activation
	asymmetric catalysis
	chiral carboxylic acid
	sulfoximine
Issue Date:	16-Aug-2021
Publisher:	Georg Thieme Verlag
Journal Title:	Synthesis
Volume:	54
Issue:	21
Start Page:	4703
End Page:	4710
Publisher DOI:	10.1055/a-1588-0072
Abstract:	Ruthenium(II)-catalyzed enantioselective C-H functionalization reactions of sulfoximines with sulfoxonium ylides are described. The combination of [RuCl2 (p-cymene)](2) and a pseudo-C-2-symmetric binaphthyl monocarboxylic acid furnished the S -chiral products in 76:24 to 92:8 er.
Rights:	This is an Accepted Manuscript of an article published by Thieme Publishing Group in Journal Title on Publication Date, available online at https://www.thieme-connect.de/products/ejournals/abstract/10.1055/a-1588-0072
Type:	article (author version)
URI:	http://hdl.handle.net/2115/87116
Appears in Collections:	薬学研究院 (Faculty of Pharmaceutical Sciences) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 吉野達彦

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