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Synthesis of C,N,N-Cyclometalated Gold(III) Complexes with Anionic Amide Ligands

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Title: Synthesis of C,N,N-Cyclometalated Gold(III) Complexes with Anionic Amide Ligands
Authors: Niizeki, Ryotaro Browse this author
Higashida, Kosuke Browse this author
Mejri, Emna Browse this author
Sawamura, Masaya Browse this author →KAKEN DB
Shimizu, Yohei Browse this author →KAKEN DB
Keywords: gold(III) complexes
pincer complexes
multicomponent reactions
chiral complexes
Issue Date: 12-Nov-2021
Publisher: Georg Thieme Verlag
Journal Title: Synlett
Volume: 33
Issue: 03
Start Page: 288
End Page: 292
Publisher DOI: 10.1055/a-1673-9236
Abstract: A series of neutral C,N,N Au(III) complexes were synthesized with N -(8-quinolinyl)benzamide derivatives or chiral N -[2-(1,3-oxazolin-2-yl)phenyl]benzamide derivatives. The convenient synthesis method for the amide ligands, together with their operationally simple complexation by direct C-H auration, permitted changes to both the steric and electronic properties of Au(III) complexes for promoting the catalytic three-component couplings of an aldehyde, an amine, and an alkyne.
Type: article (author version)
Appears in Collections:理学院・理学研究院 (Graduate School of Science / Faculty of Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 清水 洋平

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