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Synthesis of C,N,N-Cyclometalated Gold(III) Complexes with Anionic Amide Ligands
| Title: | Synthesis of C,N,N-Cyclometalated Gold(III) Complexes with Anionic Amide Ligands |
| Authors: | Niizeki, Ryotaro Browse this author | | Higashida, Kosuke Browse this author | | Mejri, Emna Browse this author | | Sawamura, Masaya Browse this author →KAKEN DB | | Shimizu, Yohei Browse this author →KAKEN DB |
| Keywords: | gold(III) complexes | | ligands | | pincer complexes | | catalysts | | multicomponent reactions | | chiral complexes |
| Issue Date: | 12-Nov-2021 |
| Publisher: | Georg Thieme Verlag |
| Journal Title: | Synlett |
| Volume: | 33 |
| Issue: | 03 |
| Start Page: | 288 |
| End Page: | 292 |
| Publisher DOI: | 10.1055/a-1673-9236 |
| Abstract: | A series of neutral C,N,N Au(III) complexes were synthesized with N -(8-quinolinyl)benzamide derivatives or chiral N -[2-(1,3-oxazolin-2-yl)phenyl]benzamide derivatives. The convenient synthesis method for the amide ligands, together with their operationally simple complexation by direct C-H auration, permitted changes to both the steric and electronic properties of Au(III) complexes for promoting the catalytic three-component couplings of an aldehyde, an amine, and an alkyne. |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/87293 |
| Appears in Collections: | 理学院・理学研究院 (Graduate School of Science / Faculty of Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 清水 洋平
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