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Surface Menshutkin S(N)2 Reaction on Basic Gold Clusters Provides Novel Opportunities for the Cationization and Functionalization of Molecular Metal Clusters
| Title: | Surface Menshutkin S(N)2 Reaction on Basic Gold Clusters Provides Novel Opportunities for the Cationization and Functionalization of Molecular Metal Clusters |
| Authors: | Narita, Kunihiro Browse this author | | Ishida, Yohei Browse this author | | Nukui, Shuichi Browse this author | | Huang, Zhong Browse this author | | Yonezawa, Tetsu Browse this author →KAKEN DB |
| Issue Date: | 2-Dec-2021 |
| Publisher: | American Chemical Society |
| Journal Title: | Journal of physical chemistry letters |
| Volume: | 12 |
| Issue: | 49 |
| Start Page: | 11761 |
| End Page: | 11765 |
| Publisher DOI: | 10.1021/acs.jpclett.1c03498 |
| Abstract: | Surface chemical reactions on atomically precise metal clusters have considerable attention for opening a new platform for cluster functionalization. In this study, basic Au-25(4-PyET)(18) (4-PyET = -SCH2CH2Py; Py = pyridyl) clusters were successfully transformed into cationized Au-25(4-PyET-CH3+)(x)(4-PyET)(18-x) clusters, without altering their Au-25 cores, through the Menshutkin S(N)2 reaction of their surface Py moieties. This study offers not only a simple cationization method but also a protocol for modifying the surface functionalities of molecular metal clusters via a synthetic reaction. |
| Rights: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of physical chemistry letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/articlesonrequest/AOR-3SYFXECXIRKIRXPB6P3K. |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/87373 |
| Appears in Collections: | 工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 石田 洋平
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