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Separate determination of arsenite and arsenate in groundwater samples by simple analytical methods

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Title: Separate determination of arsenite and arsenate in groundwater samples by simple analytical methods
Authors: Matsunaga, Koji Browse this author
Nakaya, Yuki Browse this author
Satoh, Hisashi Browse this author →KAKEN DB
Keywords: arsenate
arsenic species analysis
arsenite
groundwater
simple analytical method
Issue Date: 1-Oct-2022
Publisher: IWA Publishing
Journal Title: Water Supply
Volume: 22
Issue: 10
Start Page: 7635
End Page: 7642
Publisher DOI: 10.2166/ws.2022.331
Abstract: We investigated the interaction of As(III) with As(III)-binding DNA aptamers (Ars-3). The binding of Ars-3 to As(III) was investigated using an Ars-3 sequence and a few control DNA sequences. As a result, we conclude that Ars-3 cannot bind As(III) and As(III) can adsorb onto gold nanoparticles with selectivity. However, the As(III) concentration could be determined by a simple As(III) analysis method using Ars-3, and we measured the As(III) and As(V) concentrations separately in As(III)/As(V) mixed samples in ultrapure water and groundwater using a simple analytical method for As(III) and As(V), respectively. As(III) in the sample was measured by a simple As(III) analytical method using DNA aptamers and gold nanoparticles, and As(V) in the sample was measured by a simple As(V) analysis method using cerium oxide nanoparticles and fluorescence-labeled DNA. We can measure As(III) and As(V) concentrations in ultrapure water and groundwater in the simple analytical method for As(III) and As(V), separately.
Type: article
URI: http://hdl.handle.net/2115/87398
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

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