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Cp*Rh-III/Chiral Disulfonate/CuOAc Catalyst System for the Enantioselective Intramolecular Oxyamination of Alkenes
| Title: | Cp*Rh-III/Chiral Disulfonate/CuOAc Catalyst System for the Enantioselective Intramolecular Oxyamination of Alkenes |
| Authors: | Hirose, Jumpei Browse this author | | Wakikawa, Takumi Browse this author | | Satake, Shun Browse this author | | Kojima, Masahiro Browse this author →KAKEN DB | | Hatano, Manabu Browse this author | | Ishihara, Kazuaki Browse this author | | Yoshino, Tatsuhiko Browse this author →KAKEN DB | | Matsunaga, Shigeki Browse this author →KAKEN DB |
| Keywords: | asymmetric catalysis | | rhodium catalysis | | chiral anion | | oxyamination | | tetrahydrofuran |
| Issue Date: | 7-Dec-2021 |
| Publisher: | American Chemical Society |
| Journal Title: | ACS catalysis |
| Volume: | 11 |
| Issue: | 24 |
| Start Page: | 14702 |
| End Page: | 15251 |
| Publisher DOI: | 10.1021/acscatal.1c04699 |
| Abstract: | The enantioselective intramolecular oxyamination of unsaturated alkoxyamines using a hybrid catalytic system consisting of Cp*Rh-III/chiral disulfonate/CuOAc is described. Tetrahydrofuran derivatives with a tetrasubstituted chiral center were obtained under the optimized conditions in 91:9-97:3 er. The use of a sterically hindered chiral disulfonate and a Cu additive was essential for the high enantioselectivity. |
| Rights: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see
https://pubs.acs.org/articlesonrequest/AOR-A6FVH2CV4P9I3PH3RZBV. |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/87677 |
| Appears in Collections: | 薬学研究院 (Faculty of Pharmaceutical Sciences) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 吉野 達彦
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