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Alkali metal ion binding using cyclic polyketones

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Title: Alkali metal ion binding using cyclic polyketones
Authors: Ozawa, Narito Browse this author
Shivakumar, Kilingaru I. Browse this author
Murugavel, Muthuchamy Browse this author
Inaba, Yuya Browse this author
Yoneda, Tomoki Browse this author →KAKEN DB
Ide, Yuki Browse this author
Pirillo, Jenny Browse this author
Hijikata, Yuh Browse this author →KAKEN DB
Inokuma, Yasuhide Browse this author →KAKEN DB
Issue Date: 4-Mar-2022
Publisher: Royal Society of Chemistry
Journal Title: Chemical Communications
Volume: 58
Issue: 18
Start Page: 2971
End Page: 2974
Publisher DOI: 10.1039/D2CC00361A
Abstract: Cyclic oligoketones composed of 3,3-dimethylpentane-2,4-diones showed crown ether-like alkali metal ion binding behavior with association constants up to 1.7 x 10(4) M-1 in chloroform/acetonitrile (v/v, 9/1). The binding properties have been used for catalysis in the Finkelstein reaction in a low-polarity solvent. Furthermore, novel ion-binding hosts were generated by terminal functionalization of linear polyketones.
Type: article (author version)
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 猪熊 泰英

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