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Alkali metal ion binding using cyclic polyketones
| Title: | Alkali metal ion binding using cyclic polyketones |
| Authors: | Ozawa, Narito Browse this author | | Shivakumar, Kilingaru I. Browse this author | | Murugavel, Muthuchamy Browse this author | | Inaba, Yuya Browse this author | | Yoneda, Tomoki Browse this author →KAKEN DB | | Ide, Yuki Browse this author | | Pirillo, Jenny Browse this author | | Hijikata, Yuh Browse this author →KAKEN DB | | Inokuma, Yasuhide Browse this author →KAKEN DB |
| Issue Date: | 4-Mar-2022 |
| Publisher: | Royal Society of Chemistry |
| Journal Title: | Chemical Communications |
| Volume: | 58 |
| Issue: | 18 |
| Start Page: | 2971 |
| End Page: | 2974 |
| Publisher DOI: | 10.1039/D2CC00361A |
| Abstract: | Cyclic oligoketones composed of 3,3-dimethylpentane-2,4-diones showed crown ether-like alkali metal ion binding behavior with association constants up to 1.7 x 10(4) M-1 in chloroform/acetonitrile (v/v, 9/1). The binding properties have been used for catalysis in the Finkelstein reaction in a low-polarity solvent. Furthermore, novel ion-binding hosts were generated by terminal functionalization of linear polyketones. |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/87975 |
| Appears in Collections: | 工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 猪熊 泰英
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