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Controls on the Salinity of Sedimentary Basinal Fluids Under Constant Chemogravitational Potential Conditions

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Title: Controls on the Salinity of Sedimentary Basinal Fluids Under Constant Chemogravitational Potential Conditions
Authors: Yoshimura, Shumpei Browse this author →KAKEN DB
Keywords: sedimentary basin
salinity
chemogravitational potential
fluid
Issue Date: Mar-2023
Publisher: American Geophysical Union
Journal Title: Geochemistry geophysics geosystems
Volume: 24
Issue: 3
Start Page: e2022GC010628
Publisher DOI: 10.1029/2022GC010628
Abstract: Fluids in sedimentary basins exert a crucial influence on various geological phenomena including natural resource formation. Worldwide drilling projects have revealed that the salinity of sedimentary basinal fluids generally increases with depth, irrespective of lithology, age of sediments, or the presence of a halite bed. However, how these vertical salinity variations are produced and what controls the salinity remain unclear. This work examines a new hypothesis that downward-increasing salinity variations are a natural outcome of the constant chemogravitational potential condition. In a static environment, the salinity is distributed such that the chemogravitational potential of the solute is constant with depth. Once formed, such a distribution would be maintained because no further migration of the solute would occur. To test the hypothesis, a constant chemogravitational potential distribution model was constructed for NaCl-H2O fluids in the sediment column, and NaCl content at each depth was calculated. The results showed that NaCl content monotonically increases with depth, and the variations are similar to the trend of measured data. However, the data were not necessarily completely reproduced by the model, and deviated in some parts from the calculated profile. Such deviation may indicate fluxing of external fluid occurring in these parts, as the constant chemogravitational potential is vulnerable to an advective flow. Therefore, it is proposed that the constant chemogravitational potential condition is a possible endmember theory, influencing natural salinity variations in a static environment.
Type: article (author version)
URI: http://hdl.handle.net/2115/89349
Appears in Collections:理学院・理学研究院 (Graduate School of Science / Faculty of Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

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