Controlled helical senses of twisting in two-, three- and four-layer cyclophanes with planar chirality


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Chem. Commun._58(96)_13385-13388.pdf

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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/90941

Title:	Controlled helical senses of twisting in two-, three- and four-layer cyclophanes with planar chirality
Authors:	Katoono, Ryo Browse this author →KAKEN DB
Authors:	Shimomura, Kai Browse this author
Issue Date:	14-Dec-2022
Publisher:	Royal Society of Chemistry
Journal Title:	Chemical communications
Volume:	58
Issue:	96
Start Page:	13385
End Page:	13388
Publisher DOI:	10.1039/d2cc05742e
Abstract:	We synthesized planar chiral cyclophanes with multiple pairs of helical conformations that were generated by twisting at the interlayer. Three- and four-layer cyclophanes preferred a homochiral form with a single sense of twisting through intramolecular transmission of planar chirality. Alternatively, a heterochiral form was dominant in a two-layer cyclophane consisting of two achiral planes that were stacked orthogonally.
Type:	article (author version)
URI:	http://hdl.handle.net/2115/90941
Appears in Collections:	理学院・理学研究院 (Graduate School of Science / Faculty of Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 上遠野亮

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