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Multifunctional Triggering by Solid-Phase Molecular Motion : Relaxor Ferroelectricity, Modulation of Magnetic Exchange Interactions, and Enhancement of Negative Thermal Expansion
| Title: | Multifunctional Triggering by Solid-Phase Molecular Motion : Relaxor Ferroelectricity, Modulation of Magnetic Exchange Interactions, and Enhancement of Negative Thermal Expansion |
| Authors: | Li, Simin Browse this author | | Takahashi, Kiyonori Browse this author →KAKEN DB | | Huang, Rui-Kang Browse this author | | Xue, Chen Browse this author | | Kokado, Kenta Browse this author | | Hoshino, Norihisa Browse this author | | Akutagawa, Tomoyuki Browse this author | | Nishihara, Sadafumi Browse this author | | Nakamura, Takayoshi Browse this author |
| Issue Date: | 8-Mar-2023 |
| Publisher: | American Chemical Society |
| Journal Title: | Chemistry of materials |
| Volume: | 35 |
| Issue: | 6 |
| Start Page: | 2421 |
| End Page: | 2428 |
| Publisher DOI: | 10.1021/acs.chemmater.2c03552 |
| Abstract: | Although the development of artificial molecular machines has garnered considerable attention in recent years, the construction of multifunctional solid-state molecular machines still faces several challenges. Herein, we report a supramolecular approach as an efficient strategy for building multifunctional trigger systems. In crystals composed of [Ni(dmit)2]- with a spin of S = 1/2 and supramolecular structures consisting of 4-aminopyridinium+ and benzo[18]crown-6, supramolecular cations with dynamic degrees of freedom affect the magnetic and dielectric properties and induce negative thermal expansion (NTE). The supramolecular cations in the crystals form one-dimensional columns. Two adjacent columns form a supramolecular ladder structure via pi center dot center dot center dot pi interactions between the phenylene groups of benzo[18]crown-6 and are arranged within a two-dimensional layer. A disorder between the two sites of the phenylene ring was observed in one of the crystallographically independent benzo[18]crown-6. Disordered benzo[18]crown-6 formed polar domains within the crystal, resulting in relaxor ferroelectricity. With increasing temperature, the supramolecular ladders elongated and the translational motion of benzo[18]crown-6 caused the molecular ladder to move closer to each other. Consequently, the crystals shrunk in the direction perpendicular to the ladder, exhibiting uniaxial NTE, and the magnetic exchange interaction between the [Ni(dmit)2]- crystals was disrupted. |
| Rights: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Chemistry of materials, copyright c American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/articlesonrequest/AOR-GCAKW5R4HYHTFXUPX3QT. |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/91294 |
| Appears in Collections: | 電子科学研究所 (Research Institute for Electronic Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 高橋 仁徳
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