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Visible-Light-Induced Aminochlorination of Alkenes
| Title: | Visible-Light-Induced Aminochlorination of Alkenes |
| Authors: | Mejri, Emna Browse this author | | Higashida, Kosuke Browse this author →KAKEN DB | | Kondo, Yuta Browse this author | | Nawachi, Anna Browse this author | | Morimoto, Hiroyuki Browse this author →KAKEN DB | | Ohshima, Takashi Browse this author →KAKEN DB | | Sawamura, Masaya Browse this author →KAKEN DB | | Shimizu, Yohei Browse this author →KAKEN DB |
| Issue Date: | 8-Jun-2023 |
| Publisher: | American Chemical Society |
| Journal Title: | Organic letters |
| Volume: | 25 |
| Issue: | 24 |
| Start Page: | 4581 |
| End Page: | 4585 |
| Publisher DOI: | 10.1021/acs.orglett.3c01645 |
| Abstract: | Photoinduced N-internal vicinal aminochlorinationof styrene-type terminal alkenes was developed. The reaction proceededwithout any catalyst, and the use of N-chloro(fluorenoneimine) as both a photoactivatable aminating agent and a chlorinatingagent was essential. The imine moiety, introduced at the internalposition of the alkenes, could be hydrolyzed under mild conditionsto provide versatile beta-chlorinated primary amines, the syntheticutility of which was demonstrated by several transformations. |
| Rights: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/articlesonrequest/AOR-8QWIPN2EXP6BYIJHS2DU. |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/92591 |
| Appears in Collections: | 理学院・理学研究院 (Graduate School of Science / Faculty of Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 清水 洋平
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