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Synthesis of Functionalized Allylsilicone Compounds via Rhodium-Catalyzed Conjugate Addition of (E)- or (Z)-[3-Trimethylsilyl-1-propenyl]boronic Acids to Enones

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Title: Synthesis of Functionalized Allylsilicone Compounds via Rhodium-Catalyzed Conjugate Addition of (E)- or (Z)-[3-Trimethylsilyl-1-propenyl]boronic Acids to Enones
Authors: Yamamoto, Yasunori Browse this author →KAKEN DB
Fujita, Masayoshi Browse this author
Miyaura, Norio Browse this author
Keywords: allylsilicone
alkenylboronic acid
rhodium catalyst
conjugate addition
cyclobutanol
Issue Date: May-2002
Publisher: Georg Thieme Verlag
Journal Title: Synlett
Volume: 2000
Issue: 5
Start Page: 767
End Page: 768
Abstract: The rhodium-catalyzed conjugate addition of (E)-Me3SiCH2CH=CHB(OiPr)2 or (Z)-Me3SiCH2(C4H9)C=CHB(OiPr)2 to enones provided a novel method for the synthesis of allylsilicone compounds possessing a carbonyl group in the same molecule, which are versatile intermediates for intramolecular allylsilylation, giving cyclobutanols on treatment with Bu4NF.
Type: article (author version)
URI: http://hdl.handle.net/2115/14625
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 宮浦 憲夫

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