Synthesis of Functionalized Allylsilicone Compounds via Rhodium-Catalyzed Conjugate Addition of (E)- or (Z)-[3-Trimethylsilyl-1-propenyl]boronic Acids to Enones


Hokkaido University \| Library \| HUSCAP	Advanced Search		言語

	Home
	About HUSCAP
	Open Access Policy

	Browse by Author

Browse
	Communities & Collections

	Scholarly Journals
	Theses
	Doctoral Dissertations Listed by Graduate Schools
	Conference Procs.
	Events

	HUSCAP Senior (in Japanese)

	Societies

	Downloads (country)

For university staff
	How to post your papers to HUSCAP
	Publication of theses
	Helpline about theses publication

Open Archives Compliant

You can search our collection also at:
	Google
	Google Scholar
	CiNii
	IRDB
	OAIster
	NDLTD

Files in This Item:

synlett_2002_5_0767.pdf

90.6 kB

PDF

Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/14625

Title:	Synthesis of Functionalized Allylsilicone Compounds via Rhodium-Catalyzed Conjugate Addition of (E)- or (Z)-[3-Trimethylsilyl-1-propenyl]boronic Acids to Enones
Authors:	Yamamoto, Yasunori Browse this author →KAKEN DB
	Fujita, Masayoshi Browse this author
	Miyaura, Norio Browse this author
Keywords:	allylsilicone
	alkenylboronic acid
	rhodium catalyst
	conjugate addition
	cyclobutanol
Issue Date:	May-2002
Publisher:	Georg Thieme Verlag
Journal Title:	Synlett
Volume:	2000
Issue:	5
Start Page:	767
End Page:	768
Publisher DOI:	10.1055/s-2002-25371
Abstract:	The rhodium-catalyzed conjugate addition of (E)-Me3SiCH2CH=CHB(OiPr)2 or (Z)-Me3SiCH2(C4H9)C=CHB(OiPr)2 to enones provided a novel method for the synthesis of allylsilicone compounds possessing a carbonyl group in the same molecule, which are versatile intermediates for intramolecular allylsilylation, giving cyclobutanols on treatment with Bu4NF.
Type:	article (author version)
URI:	http://hdl.handle.net/2115/14625
Appears in Collections:	工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 宮浦憲夫

OAI-PMH ( junii2 , jpcoar_1.0 )

- Hokkaido University