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Modulable cooperativity in a valence tautomeric complex functionalized with branched alkyl chains
Title: | Modulable cooperativity in a valence tautomeric complex functionalized with branched alkyl chains |
Authors: | Kiriya, Daisuke Browse this author | Nakamura, Kohei Browse this author | Kitagawa, Susumu Browse this author | Chang, Ho-Chol Browse this author |
Issue Date: | 7-Jun-2010 |
Publisher: | Royal Society of Chemistry |
Journal Title: | Chemical Communications |
Volume: | 46 |
Issue: | 21 |
Start Page: | 3729 |
End Page: | 3731 |
Publisher DOI: | 10.1039/c001568g |
Abstract: | Functionalization of a cobalt/dioxolene complex with branched, asymmetric alkyl chains promotes non-cooperative and cooperative valence tautomerisms synchronized with thermodynamically favoured crystal-to-melt and kinetically generated glass-to-melt phase transitions, respectively, depending on the degree of crystallinity. |
Rights: | Chem. Commun., 2010, 46, 3729-3731 - Reproduced by permission of The Royal Society of Chemistry (RSC) |
Type: | article (author version) |
URI: | http://hdl.handle.net/2115/45601 |
Appears in Collections: | 理学院・理学研究院 (Graduate School of Science / Faculty of Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 張 浩徹
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