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Modulable cooperativity in a valence tautomeric complex functionalized with branched alkyl chains

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Title: Modulable cooperativity in a valence tautomeric complex functionalized with branched alkyl chains
Authors: Kiriya, Daisuke Browse this author
Nakamura, Kohei Browse this author
Kitagawa, Susumu Browse this author
Chang, Ho-Chol Browse this author
Issue Date: 7-Jun-2010
Publisher: Royal Society of Chemistry
Journal Title: Chemical Communications
Volume: 46
Issue: 21
Start Page: 3729
End Page: 3731
Publisher DOI: 10.1039/c001568g
Abstract: Functionalization of a cobalt/dioxolene complex with branched, asymmetric alkyl chains promotes non-cooperative and cooperative valence tautomerisms synchronized with thermodynamically favoured crystal-to-melt and kinetically generated glass-to-melt phase transitions, respectively, depending on the degree of crystallinity.
Rights: Chem. Commun., 2010, 46, 3729-3731 - Reproduced by permission of The Royal Society of Chemistry (RSC)
Type: article (author version)
URI: http://hdl.handle.net/2115/45601
Appears in Collections:理学院・理学研究院 (Graduate School of Science / Faculty of Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 張 浩徹

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