Conversion of MT-sulfone to a trifluoromethyl group by $IF_5^1$ : the application of an MT-sulfone anion as a trifluoromethyl anion equivalent


Hokkaido University \| Library \| HUSCAP	Advanced Search		言語

	Home
	About HUSCAP
	Open Access Policy

	Browse by Author

Browse
	Communities & Collections

	Scholarly Journals
	Theses
	Doctoral Dissertations Listed by Graduate Schools
	Conference Procs.
	Events

	HUSCAP Senior (in Japanese)

	Societies

	Downloads (country)

For university staff
	How to post your papers to HUSCAP
	Publication of theses
	Helpline about theses publication

Open Archives Compliant

You can search our collection also at:
	Google
	Google Scholar
	CiNii
	IRDB
	OAIster
	NDLTD

Files in This Item:

CC47-32_9191-9193.pdf

127.59 kB

PDF

Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/49456

Title:	Conversion of MT-sulfone to a trifluoromethyl group by $IF_5^1$ : the application of an MT-sulfone anion as a trifluoromethyl anion equivalent
Authors:	Imagawa, Yosuke Browse this author
	Yoshikawa, Syuhei Browse this author
	Fukuhara, Tadahito Browse this author
	Hara, Shoji Browse this author →KAKEN DB
Issue Date:	28-Aug-2011
Publisher:	Royal Society of Chemistry
Journal Title:	Chemical Communications
Volume:	47
Issue:	32
Start Page:	9191
End Page:	9193
Publisher DOI:	10.1039/c1cc13232f
PMID:	21748198
Abstract:	An MT-sulfone group was converted to a trifluoromethyl group by treatment with $IF_5$ after an alkylation reaction. Therefore, an MT-sulfone anion can be used as a trifluoromethyl anion equivalent. The formal asymmetric Michael-addition of a trifluoromethyl anion to crotonaldehyde was also performed.
Rights:	Chem. Commun., 2011, 47, 9191-9193 - Reproduced by permission of The Royal Society of Chemistry (RSC)
Type:	article (author version)
URI:	http://hdl.handle.net/2115/49456
Appears in Collections:	工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 原正治

OAI-PMH ( junii2 , jpcoar_1.0 )

- Hokkaido University