HUSCAP logo Hokkaido Univ. logo

Hokkaido University Collection of Scholarly and Academic Papers >
Graduate School of Engineering / Faculty of Engineering >
Peer-reviewed Journal Articles, etc >

Iridium-catalyzed borylation of arenes and heteroarenes via C-H activation

Files in This Item:
Iridium-catalyzed borylation.pdf239.82 kBPDFView/Open
Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/56360

Title: Iridium-catalyzed borylation of arenes and heteroarenes via C-H activation
Authors: Ishiyama, Tatsuo Browse this author →KAKEN DB
Miyaura, Norio Browse this author →KAKEN DB
Keywords: iridium catalyst
arylboron compounds
C–H activation
pinacolborane
bis(pinacolato) diboron
Issue Date: 2006
Journal Title: Pure and Applied Chemistry
Volume: 78
Issue: 7
Start Page: 1369
End Page: 1375
Publisher DOI: 10.1351/pac200678071369
Abstract: Direct C–H borylation of aromatic compounds catalyzed by a transition-metal complex was studied as an economical protocol for the synthesis of aromatic boron derivatives. Iridium complexes generated from Ir(I) precursors and 2,2'-bipyridine ligands efficiently catalyzed the reactions of arenes and heteroarenes with bis(pinacolato)diboron or pinacolborane to produce a variety of aryl- and heteroarylboron compounds. The catalytic cycle involves the formation of a tris(boryl)iridium(III) species and its oxidative addition to an aromatic C–H bond.
Type: article
URI: http://hdl.handle.net/2115/56360
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 石山 竜生

Export metadata:

OAI-PMH ( junii2 , jpcoar_1.0 )

MathJax is now OFF:


 

 - Hokkaido University