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BrF3-KHF2: An air-stable fluorinating reagent
| Title: | BrF3-KHF2: An air-stable fluorinating reagent |
| Authors: | Shishimi, Toru Browse this author | | Hara, Shoji Browse this author →KAKEN DB |
| Keywords: | Stable fluorinating reagent | | KHF2 | | BrF3 | | Desulfurizing fluorination |
| Issue Date: | Dec-2014 |
| Publisher: | Elsevier |
| Journal Title: | Journal of fluorine chemistry |
| Volume: | 168 |
| Start Page: | 55 |
| End Page: | 60 |
| Publisher DOI: | 10.1016/j.jfluchem.2014.08.019 |
| Abstract: | BrF3-KHF2, an air-stable solid prepared from BrF3 and KHF2, was used in the various fluorination reactions, including desulfurizing fluorination reactions of benzylic sulfides, ketone and aldehyde dithioacetals, (phenylthio)glycosides, and trimethyl trithioorthocarboxylates. As the results, one to three fluorine atoms were selectively introduced to the substrates. |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/57927 |
| Appears in Collections: | 工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 原 正治
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