Nickel(o)-Promoted Carboxylation of Allenamides with Carbon Dioxide via a Nickelalactone Intermediate


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Title:	Nickel(o)-Promoted Carboxylation of Allenamides with Carbon Dioxide via a Nickelalactone Intermediate
Authors:	Saito, Nozomi Browse this author →KAKEN DB
	Sugimura, Yasuyuki Browse this author
	Sato, Yoshihiro Browse this author →KAKEN DB
Keywords:	nickel
	allenamide
	carbon dioxide
	fixation
	β-amino acid
Issue Date:	17-Mar-2014
Publisher:	Thieme Publishing
Journal Title:	Synlett
Volume:	25
Issue:	5
Start Page:	736
End Page:	740
Publisher DOI:	10.1055/s-0033-1340628
Abstract:	Nickel(0)-promoted carboxylation of N-allenylamides (allenamides) with carbon dioxide proceeded via a nickelalactone intermediate to give beta-amino acid derivatives. It was also found that the regioselectivity at the oxidative addition stage was strongly affected by the substituents on the allene part.
Type:	article (author version)
URI:	http://hdl.handle.net/2115/58130
Appears in Collections:	薬学研究院 (Faculty of Pharmaceutical Sciences) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 齋藤望

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