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Synthesis of 1,1-Diborylalkenes through a Bronsted Base Catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron
Title: | Synthesis of 1,1-Diborylalkenes through a Bronsted Base Catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron |
Authors: | Morinaga, Akira Browse this author | Nagao, Kazunori Browse this author | Ohmiya, Hirohisa Browse this author →KAKEN DB | Sawamura, Masaya Browse this author |
Keywords: | boration | Bronsted bases | diborylalkenes | organocatalysis | synthetic methods |
Issue Date: | 21-Dec-2015 |
Publisher: | Wiley-Blackwell |
Journal Title: | Angewandte chemie-international edition |
Volume: | 54 |
Issue: | 52 |
Start Page: | 15859 |
End Page: | 15862 |
Publisher DOI: | 10.1002/anie.201509218 |
PMID: | 26564784 |
Abstract: | A method for the synthesis of 1,1-diborylalkenes through a Bronsted base catalyzed reaction between terminal alkynes and bis(pinacolato)diboron has been developed. The procedure allows direct synthesis of functionalized 1,1-diborylalkenes from various terminal alkynes including propiolates, propiolamides, and 2-ethynylazoles. |
Rights: | "Synthesis of 1,1-Diborylalkenes through a Bronsted Base Catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron", which has been published in final form at 10.1002/anie.201509218. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving (http://olabout.wiley.com/WileyCDA/Section/id-828039.html). |
Type: | article (author version) |
URI: | http://hdl.handle.net/2115/63832 |
Appears in Collections: | 理学院・理学研究院 (Graduate School of Science / Faculty of Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 大宮 寛久
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