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Synthesis of 1,1-Diborylalkenes through a Bronsted Base Catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron

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Title: Synthesis of 1,1-Diborylalkenes through a Bronsted Base Catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron
Authors: Morinaga, Akira Browse this author
Nagao, Kazunori Browse this author
Ohmiya, Hirohisa Browse this author →KAKEN DB
Sawamura, Masaya Browse this author
Keywords: boration
Bronsted bases
diborylalkenes
organocatalysis
synthetic methods
Issue Date: 21-Dec-2015
Publisher: Wiley-Blackwell
Journal Title: Angewandte chemie-international edition
Volume: 54
Issue: 52
Start Page: 15859
End Page: 15862
Publisher DOI: 10.1002/anie.201509218
PMID: 26564784
Abstract: A method for the synthesis of 1,1-diborylalkenes through a Bronsted base catalyzed reaction between terminal alkynes and bis(pinacolato)diboron has been developed. The procedure allows direct synthesis of functionalized 1,1-diborylalkenes from various terminal alkynes including propiolates, propiolamides, and 2-ethynylazoles.
Rights: "Synthesis of 1,1-Diborylalkenes through a Bronsted Base Catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron", which has been published in final form at 10.1002/anie.201509218. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving (http://olabout.wiley.com/WileyCDA/Section/id-828039.html).
Type: article (author version)
URI: http://hdl.handle.net/2115/63832
Appears in Collections:理学院・理学研究院 (Graduate School of Science / Faculty of Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 大宮 寛久

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