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Cp*Co (III) -Catalyzed C-H Functionalization and Asymmetric Reactions Using External Chiral Sources

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Title: Cp*Co (III) -Catalyzed C-H Functionalization and Asymmetric Reactions Using External Chiral Sources
Authors: Yoshino, Tatsuhiko Browse this author →KAKEN DB
Matsunaga, Shigeki Browse this author →KAKEN DB
Keywords: C-H functionalization
C-H activation
cobalt
rhodium
asymmetric catalysis
Issue Date: Jul-2019
Publisher: Georg Thieme Verlag
Journal Title: Synlett
Volume: 30
Issue: 12
Start Page: 1384
End Page: 1400
Publisher DOI: 10.1055/s-0037-1611814
Abstract: This account describes Cp*Co-III-catalyzed C-H functionalization reactions developed in our group between 2013 and 2018. Cp*Co-III-catalysts not only serve as inexpensive alternatives to Cp*Rh-III catalysts but also exhibit unique reactivity and selectivity in several transformations. In the latter part of this review, we introduce catalytic asymmetric C-H functionalization reactions using achiral Rh-III or Co-III catalysts with chiral disulfonates or carboxylic acids as external chiral sources.
Type: article (author version)
URI: http://hdl.handle.net/2115/78999
Appears in Collections:薬学研究院 (Faculty of Pharmaceutical Sciences) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 吉野 達彦

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