Cp*Ir(III)/Chiral Carboxylic Acid-Catalyzed Enantioselective C−H Alkylation of Ferrocene Carboxamides with Diazomalonates


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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/87118

Title:	Cp*Ir(III)/Chiral Carboxylic Acid-Catalyzed Enantioselective C−H Alkylation of Ferrocene Carboxamides with Diazomalonates
Authors:	Mou, Qi Browse this author
	Zhao, Ruyuan Browse this author
	Niu, Ruihan Browse this author
	Fukagawa, Seiya Browse this author
	Shigeno, Taiki Browse this author
	Yoshino, Tatsuhiko Browse this author →KAKEN DB
	Matsunaga, Shigeki Browse this author →KAKEN DB
	Sun, Bo Browse this author
Issue Date:	26-Oct-2021
Publisher:	Royal Society of Chemistry
Journal Title:	Organic chemistry frontiers
Volume:	8
Issue:	24
Start Page:	6923
End Page:	6930
Publisher DOI:	10.1039/d1qo01344k
Abstract:	Enantioselective C-H alkylation of ferrocene carboxamides with diazomalonates using an achiral CpIr(iii)/chiral carboxylic acid is described. The combination of an achiral CpIr(iii) complex and a binaphthyl-based chiral carboxylic acid provided planar chiral alkylated ferrocenes in good yields with moderate to good enantioselectivity (up to 94 : 6 er).
Type:	article (author version)
URI:	http://hdl.handle.net/2115/87118
Appears in Collections:	薬学研究院 (Faculty of Pharmaceutical Sciences) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 松永茂樹

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