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Decarbonylation through Aldehydic C–H Bond Cleavage by a Cationic Iridium Catalyst

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Title: Decarbonylation through Aldehydic C–H Bond Cleavage by a Cationic Iridium Catalyst
Authors: Shirai, Tomohiko Browse this author
Sugimoto, Kazuki Browse this author
Iwasaki, Masaya Browse this author
Sumida, Ryuki Browse this author
Fujita, Harunori Browse this author
Yamamoto, Yasunori Browse this author →KAKEN DB
Keywords: decarbonylation
iridium catalysis
C–H bond cleavage
asymmetric catalysis
Issue Date: May-2019
Publisher: Georg Thieme
Journal Title: Synlett
Volume: 30
Issue: 08
Start Page: 972
End Page: 976
Publisher DOI: 10.1055/s-0037-1611802
Abstract: We report the decarbonylation of aldehydes through an aldehydic C–H bond cleavage catalyzed by a cationic iridium/bisphosphine catalyst. The reaction proceeds under relatively mild conditions to give the corresponding hydrocarbon products in moderate to high yields. In addition, this cationic iridium catalyst system can be applied to an asymmetric hydroacylation of ketones.
Type: article (author version)
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 山本 靖典

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